Optimization, equilibrium, adsorption behavior and role of surface functional groups on graphene oxide-based nanocomposite towards diclofenac drug

Aquatic contamination of diclofenac (DCF), an emergent non-steroidal anti-inflammatory drug (NSAIDs), can result in adverse effects to many ecosystems through biomagnification. Hence, introducing effective remediation techniques to sequester the pharmaceutical wastes is highly fundamental to prevent their accumulation in the environment. Generally, adsorption has been presented as a green and efficient approach. Herein, we report the characterization and application of the novel magnetic nanocomposite ([email protected]₂O₄) derived from cobalt-based ferrite (CoFe₂O₄) and graphene oxide (GO) for DCF adsorption. For the optimization procedure, the response surface methodology (RSM) was adopted to investigate the impacts of DCF concentration (1.6–18.4 mg/L), DCF dosage (0.08–0.92 g/L), and solution pH (2.6–9.4) to find the optimum conditions for DCF removal, at 10.5 mg/L, 0.74 g/L, and pH 4, respectively. For the adsorption experiments, the kinetic, isotherm, thermodynamic, and intraparticle diffusion models were systematically studied. Moreover, we have elucidated the role of functional groups on the surface of [email protected]₂O₄ in enhancing the adsorption of DCF drug. With good removal efficiency (up to 86.1%), high maximum adsorption capacity (32.4 mg/g), [email protected]₂O₄ can be a potential candidate to eliminate DCF drug from water.     

抚顺市水污染源调查及对策分析

于2002年对抚顺市辖区内水污染源进行了调查，结果表明：抚顺市COD排放总量为5．8万吨，入浑河总量2.7万吨，氨氮总排放量为0．7万吨，入浑河总量0．2万吨．分析了造成水污染的主要原因，提出了水污染防治对策。     

SPOT图像在城市土地、人口与环境研究中的应用潜力——以北京市区为例

本文以北京市区为例。阐明了SPOT图像在城市土地、人口与环境研究中的应用潜力。笔者通过北京地区1986年3月2日的1:5万 SPOT 假彩色像片的信息量分析与其他遥感图像辨认地物的效果比较;和用于城市土地利用制图、城市人口估算的可能、分析城市土地利用与环境主要变化的研究表明:SPOT 图像比第一代资源卫星 MSS 图像具有高得多的分辨力,能够较详细反映地面实况的信息,可满足1:5万土地利用制图要求、是估算城市人口、研究城市土地利用与环境,并监测其动态变化的有效而廉价的手段,具有广阔的应用前景。     

Turbulence Perturbations in the Neutrally Stratified Surface Layer due to the Interaction of a Katabatic Flow with a Steep Ridge

Turbulence measurements were performed in Antarctica, on the Nansen Ice Sheet, dominated by westerly katabatic winds. The measurements were taken at two sites aligned with the katabatic wind fall-line. The measuring stations were located in the middle of a wide, flat iced area at a distance of 14 km from the base of a sloping surface and at the top of a steep ridge (Inexpressible Island). The aim was to investigate the perturbation of turbulence close to the ground generated by the interaction of the flow with the ridge. We present an analysis comparing the data measured at the upstream unperturbed station with those at the top of the obstacle. Moments and spectra of velocity components have been calculated for almost steady periods. The topography and roughness change produce a combined effect on the flow acceleration (of the opposite sign) and on the turbulent stresses (of the same sign). Spectra of velocity components measured at the top of the ridge and scaled by unperturbed quantities evidence an increment of energy in the high frequency subrange with respect to the up-stream flow. Moreover, the horizontal velocity components display a shift in turbulence maximum towards higher frequencies. The vertical velocity spectrum exhibits an energy increment at low frequencies with respect to the upstream spectrum.     

珠江三角洲城市人居环境测评与分析

基于人居环境系统理论,运用层次分析法构建了一个包含四个一级子系统、九个二级子系统和三十六个基层指标的珠三角城市人居环境评价指标体系.选取1997年、2000年和2002年三个时间断面对珠三角城市人居环境进行测算.结果表明,珠三角城市人居环境系统工业化中期阶段特征明显,人居环境建设开始进入软环境主导时代,但发展的协调性和稳定性明显较差.同时人居环境的改善还面临着区域产业整合带来的严峻挑战.     

菜市场噪声对周围环境的影响

南方的菜场都有从凌晨开始即进行贸易的特点，以盐城市众多菜场中最具代表性的老虎桥露天菜场为例，对菜场噪声及其对环境的影响进行了监测与评价，并提出控制措施。     

云南省地表水水化学特征及成因

对云南省主要河流、湖泊、水库等地表水的水化学特征及其分布规律进行了分析,简要分析了基本成因和影响因素.     

层次分析室内评价模型及其应用

提出了一种新的室内空气质量评价的方法———层次分析模型(IAAH)。利用IAAH法对长春部分室内空气质量进行了评价,结果表明室内空气属中等以上程度污染。     

轿车覆盖件表面瘪塘的分类及其特点

瘪塘是轿车覆盖件的主要表面缺陷之一,其产生原因涉及覆盖件结构、模具、工艺参数等诸多方面。对瘪塘进行了较为详细的描述,并根据瘪塘产生部位的特征对其进行了分类,研究了各类瘪塘的特点,为产生机理和整改方法的研究奠定了基础。     

天然水颗粒电动电位的化学模型

结合表面络合化学和双电层物理理论建立天然水颗粒电动电位(即ζ电位)与颐粒表面固有的化学性质及天然水化学条件之间的定量关系。在不同化学条件下,对均匀胶体颗粒(包括聚苯乙烯Latex颗粒和α-Fe_2O_3颗粒)进行电泳测定来验证该模型。结果表明,颗粒表面ζ电位与颗粒表面离子化官能团(—COOH或—OH)的化学性质、天然水pH值和专属吸附的阴阳离子(Ca~(2+)和PO_4~(3-))有密切关系。